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Top Quality DIETHYL BENZYLPHOSPHONATE 1080-32-6 Hot Sell In Stock
- Molecular Formula: C11H17 O3 P
- Molecular Weight: 228.228
- Appearance/Colour: CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
- Vapor Pressure: 0.00221mmHg at 25°C
- Refractive Index: n20/D 1.497(lit.)
- Boiling Point: 298.8°Cat760mmHg
- Flash Point: >113 ºC
- PSA： 45.34000
- Density: 1.095
- LogP: 3.45270
DIETHYL BENZYLPHOSPHONATE(Cas 1080-32-6) Usage
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Synthesis Reference(s) |
Tetrahedron Letters, 29, p. 1513, 1988 DOI: 10.1016/S0040-4039(00)80339-1Synthesis, p. 222, 1981 DOI: 10.1055/s-1981-29393 |
InChI:InChI=1/C11H17O3P/c1-3-13-15(12,14-4-2)10-11-8-6-5-7-9-11/h5-9H,3-4,10H2,1-2H3
1080-32-6 Relevant articles
2D Ultrafast HMBC 1H,31P: Obtaining mechanistic details on the Michaelis-Arbuzov reaction
Fernández-Valle, María Encarnación,Martínez-álvarez, Roberto,Molero-Vílchez, Dolores,Pardo, Zulay D.,Sáez-Barajas, Elena,Herrera, Antonio
, p. 799 - 805 (2015)
Ultrafast NMR spectroscopy (UF-NMR) can ...
Pseudodimeric Complexes of an (18-Crown-6)stilbene with Styryl Dyes Containing an Ammonioalkyl Group: Synthesis, Structure, and Stereospecific [2 + 2] Cross-Photocycloaddition
Martyanov, Timofey P.,Ushakov, Evgeny N.,Nuriev, Vyacheslav N.,Aleksandrova, Nadezhda A.,Sazonov, Sergey K.,Vedernikov, Artem I.,Kuz'mina, Lyudmila G.,Klimenko, Lubov S.,Martyanova, Elena G.,Gromov, Sergey P.
, p. 3164 - 3175 (2021)
A new efficient method was proposed for ...
-
Levin et al.
, p. 487 (1973)
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Lanthanoid-metal-mediated reaction of acylphosphonates: evidence for the formation of an acyllanthanoid complex
Taniguchi, Yuki,Fujii, Nobuto,Takaki, Ken,Fujiwara, Yuzo
, p. 173 - 180 (1995)
The reactions of diethyl acylphosphonate...
Crystal structures of the apo form and a complex of human LMW-PTP with a phosphonic acid provide new evidence of a secondary site potentially related to the anchorage of natural substrates
Fonseca, Emanuella M.B.,Trivella, Daniela B.B.,Scorsato, Valéria,Dias, Mariana P.,Bazzo, Natália L.,Mandapati, Kishore R.,De Oliveira, Fábio L.,Ferreira-Halder, Carmen V.,Pilli, Ronaldo A.,Miranda, Paulo C.M.L.,Aparicio, Ricardo
, p. 4462 - 4471 (2015)
Low molecular weight protein tyrosine ph...
Rapid and efficient Arbuzov reaction under microwave irradiation
Villemin, Didier,Simeon, Fabrice,Decreus, Hugues,Jaffres, Paul-Alain
, p. 209 - 213 (1998)
Diethyl alkylphosphonates are efficientl...
SIMPLE CONVERSION OF ARYL BROMIDES TO ARYLMETHYLPHOSPHONATES
Poindexter, Michael K.,Katz, Thomas J.
, p. 1513 - 1516 (1988)
Aryl bromides in tetrahydrofuran when co...
The photoisomerization of: Cis, trans -1,2-dideuterio-1,4-diphenyl-1,3-butadiene in solution. No bicycle-pedal
Saltiel, Jack,Redwood, Christopher E.,Ratheesh Kumar
, p. 2174 - 2179 (2019)
cis,trans-1,2-Dideuterio-1,4-diphenyl-1,...
Palladium-catalyzed cross-coupling reactions of organocopper derivatives of methylphosphonic esters and amides with aryl and hetaryl iodides
Lukashev,Tarasenko,Beletskaya
, p. 172 - 178 (2001)
Copper derivatives of methylphosphonic a...
Synthesis, UV/vis spectra and electrochemical characterisation of arylthio and styryl substituted ferrocenes
Sorensen, Thomas J.,Nielsen, Merete F.
, p. 610 - 618 (2011)
Two series of substituted ferrocenes wer...
Acetic acid mediated synthesis of phosphonate-substituted titanium oxo clusters
Czakler, Matthias,Artner, Christine,Schubert, Ulrich
, p. 2038 - 2045 (2014)
New phosphonate/acetate-substituted tita...
White light emission in water through admixtures of donor-π-acceptor siblings: Experiment and simulation
Kumari, Beena,Singh, Amit,Jana, Palash,Radhakrishna, Mithun,Kanvah, Sriram
, p. 11701 - 11709 (2019)
Donor-acceptor π-conjugated molecules wi...
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Mikolajczyk,M. et al.
, p. 2967 - 2972 (1979)
-
Photo-Arbuzov Rearrangements of Benzyl Phosphites
Omelanzcuk, Jan,Sopchik, Alan E.,Lee, Sueg-Geun,Akutagawa, Kunihiko,Cairns, Matthew S.,Bentrude, Wesley G.
, p. 6908 - 6909 (1988)
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Surface-mediated solid phase reactions: Microwave assisted Arbuzov rearrangement on the solid surface
Kaboudin,Balakrishna
, p. 2773 - 2776 (2001)
Microwave assisted Arbuzov rearrangement...
Copper-catalyzed synthesis of alkylphosphonates from H-phosphonates and N-tosylhydrazones
Miao, Wenjun,Gao, Yuzhen,Li, Xueqin,Gao, Yuxing,Tang, Guo,Zhao, Yufen
, p. 2659 - 2664 (2012)
A new catalytic system for the alkylatio...
Photophysical studies of substituted 1,2-diarylethenes: Twisted intramolecular charge transfer fluorescence in dimethoxycyano-substituted 1,2-diarylethene
Singh, Anil K.,Kanvah, Sriram
, p. 395 - 401 (2001)
1,2-Diarylethenes, namely (E)-1-(4-cyano...
Two trans-1-(9-anthryl)-2-phenylethene derivatives as blue-green emitting materials for highly bright organic light-emitting diodes application
Zhou, Nonglin,Shao, Xiaona,Wang, Shirong,Xiao, Yin,Li, Xianggao
, p. 228 - 238 (2017)
1-(9-Anthryl)-2-phenylethene (t-APE) is ...
Photochemical Radical C–H Halogenation of Benzyl N-Methyliminodiacetyl (MIDA) Boronates: Synthesis of α-Functionalized Alkyl Boronates
Yang, Ling,Tan, Dong-Hang,Fan, Wen-Xin,Liu, Xu-Ge,Wu, Jia-Qiang,Huang, Zhi-Shu,Li, Qingjiang,Wang, Honggen
, p. 3454 - 3458 (2021)
α-Haloboronates are useful organic synth...
-
Rabinowitz,R.
, p. 2975 - 2978 (1963)
-
Lewis acid catalyzed room-temperature Michaelis-Arbuzov rearrangement
Renard, Pierre-Yves,Vayron, Philippe,Leclerc, Eric,Valleix, Alain,Mioskowski, Charles
, p. 2389 - 2392 (2003)
The taming of the shrew! For the first t...
Microwave irradiation in organophosphorus chemistry. III. Moderate scale synthesis of reagents for olefin formation
Kiddle
, p. 3377 - 3382 (2001)
Representative phosphonates and phosphon...
Advantages of organophosphorus synthesis in ionic liquids: "Green" approaches to useful phosphorus-substituted building blocks
Odinets,Matveeva,Sharova,Artyushin,Kozlov,Vorob'eva,Osipov,Roeschenthaler
, p. 383 - 388 (2008)
Novel examples concerning the applicatio...
Palladium-catalyzed copper(I) salt-mediated arylation of a bis(dimethylamino)phosphonyl-stabilized carbanion
Tarasenko, Elena A.,Lukashev, Nikolai V.,Beletskaya, Irina P.
, p. 1611 - 1613 (2000)
The synthesis of new arylmethylphosphoni...
-
Seus,Wilson
, p. 5243 (1961)
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Color tuning of doped PLEDs by energy transfer from PVK to dopant constituted with biphenyl and butadienyl unit
Han, Yoon Soo,Kim, Hoyoung,Choi, Byeong Dae,Kwon, Younghwan,Hur, Youngjune,Kwak, Giseop,Kim, Soon Hak,Park, Lee Soon,Choi, Byeong-Dae
, p. 341 - 351 (2007)
A dopant, 4,4'-bis(dimethyl[4-(2-phenyl-...
Ionic-liquid-promoted Michaelis-Arbuzov rearrangement
Matveeva,Odinets,Kozlov,Shaplov,Mastryukova
, p. 7645 - 7648 (2006)
Room-temperature imidazolium ionic liqui...
Identification of novel non-nucleoside vinyl-stilbene analogs as potent norovirus replication inhibitors with a potential host-targeting mechanism
Harmalkar, Dipesh S.,Lee, Sung-Jin,Lu, Qili,Kim, Mi Il,Park, Jaehyung,Lee, Hwayoung,Park, Minkyung,Lee, Ahrim,Lee, Choongho,Lee, Kyeong
, (2019)
Norovirus (NV), is the most common cause...
Vinyl-Stilbene Compounds and Uses Thereof
-
Paragraph 0255-0262, (2021/06/22)
The present invention relates to a biphe...
Determination and application of the excited-state substituent constants of pyridyl and substituted phenyl groups
Cao, Chao-Tun,Yan, Lu,Cao, Chenzhong
, (2021/05/21)
Thirty six 1-pyridyl-2-arylethenes XCH=C...
1080-32-6 Process route
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100-39-0
benzyl bromide
-
-
122-52-1
triethyl phosphite
-
-
1080-32-6
O,O-diethyl benzylphosphonate
-
-
18933-98-7
benzylphosphonic acid monoethyl ester
-
-
762-04-9
phosphonic acid diethyl ester
-
-
15845-66-6
Ethylphosphorige Saeure
| Conditions | Yield |
|---|---|
|
With
1-butyl-3-methylimidazolium trifluoromethanesulfonimide;
at 110 ℃;
for 0.333333h;
Further Variations:;
Temperatures;
Solvents;
Reagents;
Product distribution;
|
-
-
100-51-6,185532-71-2
benzyl alcohol
-
-
122-52-1
triethyl phosphite
-
-
103-50-4
dibenzyl ether
-
-
2768-31-2
benzyl diethyl phosphite
-
-
539-30-0
1-(ethoxymethyl)benzene
-
-
1080-32-6
O,O-diethyl benzylphosphonate
| Conditions | Yield |
|---|---|
|
With
tetrabutylammomium bromide;
In
neat (no solvent);
at 125 ℃;
for 4h;
Inert atmosphere;
Schlenk technique;
Sealed tube;
Green chemistry;
|
1080-32-6 Upstream products
-
60-29-7
diethyl ether
-
2303-76-6
sodium diethyl phosphite
-
100-44-7
benzyl chloride
-
122-52-1
triethyl phosphite
1080-32-6 Downstream products
-
58-72-0
Triphenylethylene
-
100267-38-7
4-diethoxyphosphoryl-3,4-diphenyl-butyric acid ethyl ester
-
100-29-8
1-ethoxy-4-nitrobenzene
-
18406-56-9
Bis(trimethylsilyl) benzylphosphonate
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