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Offer Chemical Raw Material (TOLUENE)TRICARBONYLCHROMIUM 12083-24-8 In Stock
- Molecular Formula: C10H8 Cr O3
- Molecular Weight: 228.168
-
Melting Point:
78-82 °C(lit.)
- Flash Point: 170 °F
- PSA: 0.00000
- LogP: 1.37100
12083-24-8 Relevant articles
Photoinduced [6 + 2] cycloadditions of alkynes to tricarbonyl(cycloheptatriene)chromium(0)
Chaffee, Karen,Sheridan, John B.,Aistars, Arnis
, p. 18 - 19 (1992)
Photolysis of [(η6-C7H8)Cr(CO)3] (1) and...
Syntheses, crystal structures, and density functional theory calculations of the closo-[1-M(CO)3(η4-E9)]4- (E = Sn, Pb; M = Mo, W) cluster anions and solution NMR spectroscopic characterization of [1-M(CO)3(η4-Sn9)]4- (M = Cr, Mo, W)
Campbell, Janette,Mercier, Helene P.A.,Franke, Holger,Santry, David P.,Dixon, David A.,Schrobilgen, Gary J.
, p. 86 - 107 (2002)
The closo-[1-M(CO)3(η4-E9)]4- (E = Sn, P...
Stability and the gas chromatography of alkyl-substituted η6-benzenetricarbonylchromium(0) complexes
Patsalides, E.,Pratten, S. J.,Robards, K.
, p. 169 - 180 (1989)
Thermoanalytical and gas chromatographic...
The reactions of group VI metal carbonyls with pyrrolidine, piperazine, and morpholine
Fowles,Jenkins
, p. 257 - 259 (1964)
Pyrrolidine and morpholine react with gr...
Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0)
Goti, Andrea,Semmelhack, Martin F.
, p. C4 - C7 (1994)
Arene displacement from the title comple...
A KINETIC INVESTIGATION OF ARENE EXCHANGE AND SUBSTITUTION IN (NAPHTHALENE)Cr(CO)3
Howell, James A. S.,Dixon, Denis T.,Kola, John C.,Ashford, Neil F.
, p. C1 - C4 (1985)
The rate of (naphthalene)Cr(CO)3 with to...
Reactivity of some "ladder" type complexes under conditions of metallation
Orlova,Nekrasov,Petrovskii,Ezernitskaya,Magdesieva,Milovanov,Butin
, p. 1785 - 1788 (1998)
The behavior of binuclear "ladder" type ...
Organometallic chemistry in supercritical fluids: The generation and detection of dinitrogen and nonclassical dihydrogen complexes of group 6, 7, and 8 transition metals at room temperature
Howdle, Steven M.,Healy, Michael A.,Poliakoff, Martyn
, p. 4804 - 4813 (1990)
The complete miscibility of N2 and H2 wi...
N -heteropolycyclic compounds from the formal intramolecular (4 + 1)-cycloaddition of chromium aminocarbenes
Dery, Martin,Lefebvre, Louis-Philippe D.,Aissa, Kevin,Spino, Claude
supporting information, p. 5456 - 5459 (2013/11/19)
Chromium aminocarbenes tethered to diene...
Palladium-catalyzed allylic substitution with (η6-Arene- CH2Z)Cr(CO)3-based nucleophiles
Zhang, Jiadi,Stanciu, Corneliu,Wang, Beibei,Hussain, Mahmud M.,Da, Chao-Shan,Carroll, Patrick J.,Dreher, Spencer D.,Walsh, Patrick J.
, p. 20552 - 20560 (2012/02/13)
Although the palladium-catalyzed Tsuji-T...
SYSTEM AND METHOD FOR SUPPRESSING SUBLIMATION OF MATERIALS DURING CHEMICAL TRANSFORMATION AT HIGH TEMPERATURES
-
Page/Page column 2, (2009/12/27)
An apparatus for use in reactions of mat...
(η6-Arene)tricarbonylchromium and ferrocene complexes linked to binaphthyl derivatives
Germaneau, Romain,Chavignon, Rene,Tranchier, Jean-Philippe,Rose-Munch, Francoise,Rose, Eric,Collot, Mayeul,Duhayon, Carine
, p. 6139 - 6149 (2008/10/09)
Palladium-catalyzed coupling reactions o...
12083-24-8 Process route
-
-
199620-14-9,13007-92-6
chromium(0) hexacarbonyl
-
-
108-88-3,15644-74-3,16713-13-6
toluene
-
-
12083-24-8
tricarbonyl(η(6)-toluene)chromium
-
-
628-52-4,17593-70-3
chromium(II) acetate
| Conditions | Yield |
|---|---|
|
With
acetic acid;
In
decalin;
refluxing for 2.75 h;
|
83%
|
-
-
93-58-3,5705-52-2,80226-58-0
benzoic acid methyl ester
-
-
199620-14-9,13007-92-6
chromium(0) hexacarbonyl
-
-
697302-50-4,697302-51-5,12082-08-5,697302-53-7
(benzene)tricarbonylchromium
-
-
12083-24-8
tricarbonyl(η(6)-toluene)chromium
-
-
12125-87-0
(methylbenzoate)chromium tricarbonyl
| Conditions | Yield |
|---|---|
|
In
tetrahydrofuran;
refluxing in THF for 62 h at 130°C; extn. of solvent, chromy. (SiO2, hexane/benzene/ether (5:1:1)), IR, (1)H-NMR;
|
50%
|
12083-24-8 Upstream products
-
199620-14-9
chromium(0) hexacarbonyl
-
108-88-3
toluene
-
5720-05-8
4-methylphenylboronic acid
-
5084-80-0
tri(4-tolyl)boroxine
12083-24-8 Downstream products
-
24554-61-8
((CH3 )2AsC6 H5 )3Cr(CO)3
-
12155-45-2
(trans-stilbene)tricarbonylchromium
-
33197-63-6
(C6 H5 CH2 C(O)C6 H5 )Cr(CO)3
-
82067-23-0
C6 H5 CH2 CH(OH)C6 H5 Cr(CO)3
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