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(TOLUENE)TRICARBONYLCHROMIUM

  • CAS:12083-24-8
  • purity:99%
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Offer Chemical Raw Material (TOLUENE)TRICARBONYLCHROMIUM 12083-24-8 In Stock

  • Molecular Formula: C10H8 Cr O3
  • Molecular Weight: 228.168
  • Melting Point: 78-82 °C(lit.)
     
  • Flash Point: 170 °F  
  • PSA: 0.00000 
  • LogP: 1.37100 

12083-24-8 Relevant articles

Photoinduced [6 + 2] cycloadditions of alkynes to tricarbonyl(cycloheptatriene)chromium(0)

Chaffee, Karen,Sheridan, John B.,Aistars, Arnis

, p. 18 - 19 (1992)

Photolysis of [(η6-C7H8)Cr(CO)3] (1) and...

Syntheses, crystal structures, and density functional theory calculations of the closo-[1-M(CO)3(η4-E9)]4- (E = Sn, Pb; M = Mo, W) cluster anions and solution NMR spectroscopic characterization of [1-M(CO)3(η4-Sn9)]4- (M = Cr, Mo, W)

Campbell, Janette,Mercier, Helene P.A.,Franke, Holger,Santry, David P.,Dixon, David A.,Schrobilgen, Gary J.

, p. 86 - 107 (2002)

The closo-[1-M(CO)3(η4-E9)]4- (E = Sn, P...

Stability and the gas chromatography of alkyl-substituted η6-benzenetricarbonylchromium(0) complexes

Patsalides, E.,Pratten, S. J.,Robards, K.

, p. 169 - 180 (1989)

Thermoanalytical and gas chromatographic...

The reactions of group VI metal carbonyls with pyrrolidine, piperazine, and morpholine

Fowles,Jenkins

, p. 257 - 259 (1964)

Pyrrolidine and morpholine react with gr...

Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0)

Goti, Andrea,Semmelhack, Martin F.

, p. C4 - C7 (1994)

Arene displacement from the title comple...

A KINETIC INVESTIGATION OF ARENE EXCHANGE AND SUBSTITUTION IN (NAPHTHALENE)Cr(CO)3

Howell, James A. S.,Dixon, Denis T.,Kola, John C.,Ashford, Neil F.

, p. C1 - C4 (1985)

The rate of (naphthalene)Cr(CO)3 with to...

Reactivity of some "ladder" type complexes under conditions of metallation

Orlova,Nekrasov,Petrovskii,Ezernitskaya,Magdesieva,Milovanov,Butin

, p. 1785 - 1788 (1998)

The behavior of binuclear "ladder" type ...

Organometallic chemistry in supercritical fluids: The generation and detection of dinitrogen and nonclassical dihydrogen complexes of group 6, 7, and 8 transition metals at room temperature

Howdle, Steven M.,Healy, Michael A.,Poliakoff, Martyn

, p. 4804 - 4813 (1990)

The complete miscibility of N2 and H2 wi...

N -heteropolycyclic compounds from the formal intramolecular (4 + 1)-cycloaddition of chromium aminocarbenes

Dery, Martin,Lefebvre, Louis-Philippe D.,Aissa, Kevin,Spino, Claude

supporting information, p. 5456 - 5459 (2013/11/19)

Chromium aminocarbenes tethered to diene...

Palladium-catalyzed allylic substitution with (η6-Arene- CH2Z)Cr(CO)3-based nucleophiles

Zhang, Jiadi,Stanciu, Corneliu,Wang, Beibei,Hussain, Mahmud M.,Da, Chao-Shan,Carroll, Patrick J.,Dreher, Spencer D.,Walsh, Patrick J.

, p. 20552 - 20560 (2012/02/13)

Although the palladium-catalyzed Tsuji-T...

SYSTEM AND METHOD FOR SUPPRESSING SUBLIMATION OF MATERIALS DURING CHEMICAL TRANSFORMATION AT HIGH TEMPERATURES

-

Page/Page column 2, (2009/12/27)

An apparatus for use in reactions of mat...

(η6-Arene)tricarbonylchromium and ferrocene complexes linked to binaphthyl derivatives

Germaneau, Romain,Chavignon, Rene,Tranchier, Jean-Philippe,Rose-Munch, Francoise,Rose, Eric,Collot, Mayeul,Duhayon, Carine

, p. 6139 - 6149 (2008/10/09)

Palladium-catalyzed coupling reactions o...

12083-24-8 Process route

chromium<sup>(0)</sup> hexacarbonyl
199620-14-9,13007-92-6

chromium(0) hexacarbonyl

toluene
108-88-3,15644-74-3,16713-13-6

toluene

tricarbonyl(η(6)-toluene)chromium
12083-24-8

tricarbonyl(η(6)-toluene)chromium

chromium(II) acetate
628-52-4,17593-70-3

chromium(II) acetate

Conditions
Conditions Yield
With acetic acid; In decalin; refluxing for 2.75 h;
83%
benzoic acid methyl ester
93-58-3,5705-52-2,80226-58-0

benzoic acid methyl ester

chromium<sup>(0)</sup> hexacarbonyl
199620-14-9,13007-92-6

chromium(0) hexacarbonyl

(benzene)tricarbonylchromium
697302-50-4,697302-51-5,12082-08-5,697302-53-7

(benzene)tricarbonylchromium

tricarbonyl(η(6)-toluene)chromium
12083-24-8

tricarbonyl(η(6)-toluene)chromium

(methylbenzoate)chromium tricarbonyl
12125-87-0

(methylbenzoate)chromium tricarbonyl

Conditions
Conditions Yield
In tetrahydrofuran; refluxing in THF for 62 h at 130°C; extn. of solvent, chromy. (SiO2, hexane/benzene/ether (5:1:1)), IR, (1)H-NMR;
50%

12083-24-8 Upstream products

  • 199620-14-9
    199620-14-9

    chromium(0) hexacarbonyl

  • 108-88-3
    108-88-3

    toluene

  • 5720-05-8
    5720-05-8

    4-methylphenylboronic acid

  • 5084-80-0
    5084-80-0

    tri(4-tolyl)boroxine

12083-24-8 Downstream products

  • 24554-61-8
    24554-61-8

    ((CH3 )2AsC6 H5 )3Cr(CO)3

  • 12155-45-2
    12155-45-2

    (trans-stilbene)tricarbonylchromium

  • 33197-63-6
    33197-63-6

    (C6 H5 CH2 C(O)C6 H5 )Cr(CO)3

  • 82067-23-0
    82067-23-0

    C6 H5 CH2 CH(OH)C6 H5 Cr(CO)3

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